Lifeboat Foundation

Transitioning from fossil fuels to a clean hydrogen economy will require cheaper and more efficient ways to use renewable sources of electricity to break water into hydrogen and oxygen.

But a key step in that process, known as the oxygen evolution reaction or OER, has proven to be a bottleneck. Today it’s only about 75% efficient, and the precious metal catalysts used to accelerate the reaction, like platinum and iridium, are rare and expensive.

Now an international team led by scientists at Stanford University and the Department of Energy’s SLAC National Accelerator Laboratory has developed a suite of advanced tools to break through this bottleneck and improve other energy-related processes, such as finding ways to make lithium-ion batteries charge faster. The research team described their work in Nature today.

In work that could someday turn cell phones into sensors capable of detecting viruses and other minuscule objects, MIT researchers have built a powerful nanoscale flashlight on a chip.

Their approach to designing the tiny light beam on a chip could also be used to create a variety of other nano flashlights with different beam characteristics for different applications. Think of a wide spotlight versus a beam of light focused on a single point.

For many decades, scientists have used light to identify a material by observing how that light interacts with the material. They do so by essentially shining a beam of light on the material, then analyzing that light after it passes through the material. Because all materials interact with light differently, an analysis of the light that passes through the material provides a kind of “fingerprint” for that material. Imagine doing this for several colors — i.e., several wavelengths of light — and capturing the interaction of light with the material for each color. That would lead to a fingerprint that is even more detailed.

Researchers at CRANN (The Centre for Research on Adaptive Nanostructures and Nanodevices), and the School of Physics at Trinity College Dublin, today announced that a magnetic material developed at the Centre demonstrates the fastest magnetic switching ever recorded.

The team used femtosecond laser systems in the Photonics Research Laboratory at CRANN to switch and then re-switch the magnetic orientation of their material in trillionths of a second, six times faster than the previous record, and a hundred times faster than the clock speed of a personal computer.

This discovery demonstrates the potential of the material for a new generation of energy efficient ultra-fast computers and data storage systems.

In a feat worthy of a laboratory conceived by J.K. Rowling, MIT researchers and colleagues have turned a “magic” material composed of atomically thin layers of carbon into three useful electronic devices. Normally, such devices, all key to the quantum electronics industry, are created using a variety of materials that require multiple fabrication steps. The MIT approach automatically solves a variety of problems associated with those more complicated processes.

As a result, the work could usher in a new generation of quantum electronic devices for applications including quantum computing. Further, the devices can be superconducting, or conduct electricity without resistance. They do so, however, through an unconventional mechanism that, with further study, could give new insights into the physics of superconductivity. The researchers report their results in the May 3, 2021 issue of Nature Nanotechnology.

“In this work we have demonstrated that magic angle graphene is the most versatile of all superconducting materials, allowing us to realize in a single system a multitude of quantum electronic devices. Using this advanced platform, we have been able to explore for the first time novel superconducting physics that only appears in two dimensions,” says Pablo Jarillo-Herrero, the Cecil and Ida Green Professor of Physics at MIT and leader of the work. Jarillo-Herrero is also affiliated with MIT’s Materials Research Laboratory.

Chemical organization in reaction-diffusion systems offer a strategy to generate materials with ordered morphologies and architecture. Periodic structures can be formed using molecules or nanoparticles. An emerging frontier in materials science aims to combine nanoparticles and molecules. In a new report on Science Advances, Amanda J. Ackroyd and a team of scientists in chemistry, physics and nanomaterials in Canada, Hungary and the U.S. noted how solvent evaporation from a suspension of cellulose nanocrystals (CNCs) and L-(+)-tartaric acid [abbreviated L-(+)-TA] caused the phase separation of precipitation to result in the rhythmic alteration of CNC-rich, L-(+)-TA rings. The CNC-rich regions maintained a cholesteric structure, while the L-(+)-TA-rich bands formed via radially elongated bundles to expand the knowledge of self-organizing reaction-diffusion systems and offer a strategy to design self-organizing materials.

Chemical organization

The process of self-organization and self-assembly occurs universally in non-equilibrium systems of living matter, geochemical environments, materials science and in industry. Existing experiments that lead to periodic structures can be divided into two groups including the classical Liesegang-type experiments and chemical organization via periodic precipitation to generate materials with ordered morphologies and structural hierarchy. In this work, Ackroyd et al. developed a strategy for solvent evaporation to phase separate an aqueous solution of tartaric acid/cellulose nanocrystals [L-(+)-TA/CNC or TA/CNC] for its subsequent precipitation to result in a rhythmic alternation of CNC-rich or CNC-depleted ring-type regions. The team developed a kinetic model which agreed with the experimental results quantitatively. The work expands the range of self-organizing reaction-diffusion systems to pave the way for periodically structured functional materials.

Getting closer.

Drugs and vaccines circulate through the vascular system reacting according to their chemical and structural nature. In some cases, they are intended to diffuse. In other cases, like cancer treatments, the intended target is highly localized. The effectiveness of a medicine —and how much is needed and the side effects it causes —are a function of how well it can reach its target.

“A lot of medicines involve intravenous injections of drug carriers,” said Ying Li, an assistant professor of mechanical engineering at the University of Connecticut. “We want them to be able to circulate and find the right place at the right time and to release the right amount of drugs to safely protect us. If you make mistakes, there can be terrible side effects.”

Continue reading “Targeting tumors with nanoworms” »

Circa 2020 o.o!

Japanese researchers have had success with miniscule robots that are small enough to get inside and neutralize a cancer cell — and they want their creations to be ready to deal with future outbreaks of lethal viruses.

Multi-resistant pathogens are a serious and increasing problem in today’s medicine. Where antibiotics are ineffective, these bacteria can cause life-threatening infections. Researchers at Empa and ETH Zurich are currently developing nanoparticles that can be used to detect and kill multi-resistant pathogens that hide inside our body cells. The team published the study in the current issue of the journal Nanoscale (“Inorganic nanohybrids combat antibiotic-resistant bacteria hiding within human macrophages”).

Antibiotic-resistant bacteria are being swallowed by a human white blood cell. Colorized, scanning electron microscopic (SEM) image. (Image: CDC/NIAID)

In the arms race “mankind against bacteria”, bacteria are currently ahead of us. Our former miracle weapons, antibiotics, are failing more and more frequently when germs use tricky maneuvers to protect themselves from the effects of these drugs. Some species even retreat into the inside of human cells, where they remain “invisible” to the immune system. These particularly dreaded pathogens include multi-resistant staphylococci (MRSA), which can cause life-threatening diseases such as sepsis or pneumonia.

Scientists at Osaka University, in cooperation with Joanneum Research (Weiz, Austria), have developed wireless health monitoring patches that use embedded piezoelectric nanogenerators to power themselves with harvested biomechanical energy. This work may lead to new autonomous health sensors as well as battery-free wearable electronic devices.

As wearable technology and smart sensors become increasingly popular, the problem of providing power to all of these devices become more relevant. While the energy requirements of each component may be modest, the need for wires or even batteries become burdensome and inconvenient. That is why new energy harvesting methods are needed. Also, the ability for integrated health monitors to use ambient motion to both power and activate sensors will help accelerate their adoption in doctor’s offices.

Now, an international team of researchers from Japan and Austria has invented new ultraflexible patches with a ferroelectric polymer that can not only sense a patient’s pulse and blood pressure, but also power themselves from normal movements. The key was starting with a substrate just one micron thick. Using a strong electric field, ferroelectric crystalline domains in a copolymer were aligned so that the sample had a large electric dipole moment. Based on the piezoelectric effect, which is very efficient in converting natural motion into small electric voltages, the device responds rapidly to strain or pressure changes. These voltages can be transduced either into signals for the medical sensors or to directly harvest the energy. “Our e-health patches may be employed as part of screening for lifestyle-related diseases such as heart disorders, signs of stress, and sleep apnea,” first-author Andreas Petritz says.