A research team affiliated with UNIST has developed stable and efficient chalcogenide-based photoelectrodes, addressing a longstanding challenge of corrosion. This advancement paves the way for the commercial viability of solar-driven water splitting technology—producing hydrogen directly from sunlight without electrical input.
Jointly led by Professors Ji-Wook Jang and Sung-Yeon Jang from the School of Energy and Chemical Engineering, the team reported a highly durable, corrosion-resistant metal-encapsulated PbS quantum dot (PbS-QD) solar cell-based photoelectrode that delivers both high photocurrent and long-term operational stability for photoelectrochemical (PEC) water splitting without the need for sacrificial agents. The research is published in the journal Nature Communications.
PEC water splitting is a promising route for sustainable hydrogen production, where sunlight is used to drive the decomposition of water into hydrogen and oxygen within an electrolyte solution. The efficiency of this process depends heavily on the stability of the semiconductor material in the photoelectrode, which absorbs sunlight and facilitates the electrochemical reactions. Although chalcogenide-based sulfides, like PbS are highly valued for their excellent light absorption and charge transport properties, they are prone to oxidation and degradation when submerged in water, limiting their operational stability.









