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Category: chemistry

Blue jean dye could make batteries greener

Sustainability is often described in shades of green, but the future of clean energy may also carry a hint of deep blue. Electric vehicles and energy storage systems could soon draw power from a familiar pigment found in denim.

Concordia researchers have found that indigo, the natural dye used to color fabrics for centuries, can help shape the future of safe and sustainable batteries. In a study published in Nature Communications, the team revealed that the common substance supports two essential reactions inside a solid-state battery at the same time. This behavior helps the battery hold more energy, cycle reliably and perform well even in cold conditions.

“We were excited to see that a natural molecule could guide the battery chemistry instead of disrupting it,” says Xia Li, the study’s lead author and associate professor in the Department of Chemical and Materials Engineering. “Indigo helps the battery work in a very steady and predictable way. That is important if we want greener materials to play a role in future energy systems.”

Sum-frequency microscope can image an invisible 2D material

Researchers from the Physical Chemistry and Theory departments at the Fritz Haber Institute have found a new way to image layers of boron nitride that are only a single atom thick. This material is usually nearly invisible in optical microscopes because it has no optical resonances.

Electrons stay put in layers of mismatched ‘quantum Legos’

Electrons can be elusive, but Cornell researchers using a new computational method can now account for where they go—or don’t go—in certain layered materials.

Physics and engineering researchers have confirmed that in certain quantum materials, known as “misfits” because their crystal structures don’t align perfectly—picture LEGOs where one layer has a square grid and the other a hexagonal grid—electrons mostly stay in their home layers.

This discovery, important for designing materials with quantum properties including superconductivity, overturns a long-standing assumption. For years, scientists believed that large shifts in energy bands in certain misfit materials meant electrons were physically moving from one layer to the other. But the Cornell researchers have found that chemical bonding between the mismatched layers causes electrons to rearrange in a way that increases the number of high-energy electrons, while few electrons move from one layer to the other.

SCFFBXW11 Complex Targets Interleukin-17 Receptor A for Ubiquitin–Proteasome-Mediated Degradation

Interleukin-17 (IL-17) is a pro-inflammatory cytokine that participates in innate and adaptive immune responses and plays an important role in host defense, autoimmune diseases, tissue regeneration, metabolic regulation, and tumor progression. Post-translational modifications (PTMs) are crucial for protein function, stability, cellular localization, cellular transduction, and cell death. However, PTMs of IL-17 receptor A (IL-17RA) have not been investigated. Here, we show that human IL-17RA was targeted by F-box and WD repeat domain-containing 11 (FBXW11) for ubiquitination, followed by proteasome-mediated degradation. We used bioinformatics tools and biochemical techniques to determine that FBXW11 ubiquitinated IL-17RA through a lysine 27-linked polyubiquitin chain, targeting IL-17RA for proteasomal degradation.

Taxonomy of Bacteria: Identification and Classification

We’ve been looking at bacteria for a few centuries now, so how do we categorize them? We love to classify things and put them in groups, so how does that work for bacteria? Well let’s learn about Gram-staining, antigens, other phenotypic and genotypic properties, and we will be well on our way to understanding this process!

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Ceramic electrochemical cell production temperature drops by over 500°C with new method

As power demand surges in the AI era, the protonic ceramic electrochemical cell (PCEC), which can simultaneously produce electricity and hydrogen, is gaining attention as a next-generation energy technology. However, this cell has faced the technical limitation of requiring an ultra-high production temperature of 1,500°C.

A KAIST research team has succeeded in establishing a new manufacturing process that lowers this limit by more than 500°C for the first time.

Tiny Earthquakes Spark a Microbial Awakening Beneath Yellowstone

Researchers studying Yellowstone’s depths discovered that small earthquakes can recharge underground microbial life.

The quakes exposed new rock and fluids, creating bursts of chemical energy that microbes can use. Both the water chemistry and the microbial communities shifted dramatically in response. This dynamic may help explain how life survives in deep, dark environments.

A large portion of earth’s life lives underground.

Total Synthesis and Anticancer Study of (+)-Verticillin AClick to copy article linkArticle link copied!

For the first time, MIT chemists have synthesized a fungal compound known as verticillin A, which was discovered more than 50 years ago and has shown potential as an anticancer agent.

The compound has a complex structure that made it more difficult to synthesize than related compounds, even though it differed by only a couple of atoms.

“We have a much better appreciation for how those subtle structural changes can significantly increase the synthetic challenge,” says Mohammad Movassaghi, an MIT professor of chemistry. “Now we have the technology where we can not only access them for the first time, more than 50 years after they were isolated, but also we can make many designed variants, which can enable further detailed studies.”

In tests in human cancer cells, a derivative of verticillin A showed particular promise against a type of pediatric brain cancer called diffuse midline glioma. More tests will be needed to evaluate its potential for clinical use, the researchers say.

Movassaghi and Jun Qi, an associate professor of medicine at Dana-Farber Cancer Institute/Boston Children’s Cancer and Blood Disorders Center and Harvard Medical School, are the senior authors of the study, which appears today in the Journal of the American Chemical Society. Walker Knauss PhD ’24 is the lead author of the paper. Xiuqi Wang, a medicinal chemist and chemical biologist at Dana-Farber, and Mariella Filbin, research director in the Pediatric Neurology-Oncology Program at Dana-Farber/Boston Children’s Cancer and Blood Disorders Center, are also authors of the study.

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