Artificial photosynthesis is a technology with immense potential that aims to emulate the natural photosynthetic process. The process of natural photosynthesis involves the conversion of solar energy into chemical energy, which is stored in organic compounds. Catalysis is an essential aspect of artificial photosynthesis, as it facilitates the reactions that convert solar energy into chemical energy. In this review, we aim to provide an extensive overview of recent developments in the field of artificial photosynthesis by catalysis. We will discuss the various catalyst types used in artificial photosynthesis, including homogeneous catalysts, heterogeneous catalysts, and biocatalysts.

All-perovskite tandem solar cells (TSCs) are a class of solar cells comprised of two or more sub-cells that absorb light with different wavelengths, all of which are made of perovskites (i.e., materials with a characteristic crystal structure known to efficiently absorb light). These solar cells have been found to be highly promising energy solutions, as they could convert sunlight into electricity more efficiently than existing silicon-based solar cells.

Despite their potential, most all-perovskite TSCs developed to date only perform well when they are small and their performance rapidly declines as their size increases. This has ultimately prevented them from being manufactured and deployed on a large-scale.

Researchers at Wuhan University and other institutes in China recently introduced a new strategy for enhancing the performance of all-perovskite TSCs irrespective of their size, which could in turn contribute to their future commercialization. Their proposed approach for fabricating these cells, outlined in a paper published in Nature Nanotechnology, entails the use of piracetam, a chemical additive that can help to control the initial phase of crystal formation (i.e., nucleation) in wide-bandgap perovskites.

Solar power has long been a beacon of hope in our pursuit of clean energy. However, the road to sustainable, high-efficiency photovoltaics has been riddled with roadblocks such as toxicity and instability in widely used lead halide perovskites. Could we engineer a solar cell that delivers not just high performance, but also durability, stability and environmental safety?

That question led us to (Ca, Ba)ZrS₃, a chalcogenide perovskite with immense promise. Unlike its lead-based counterparts, this material boasts strong thermal and chemical stability. More importantly, its bandgap can be finely tuned down to 1.26 eV with less than 2% calcium doping, placing it squarely within the Shockley-Queisser limit for optimal photovoltaic conversion.

For the first time, my research team at the Autonomous University of Querétaro explored an innovative idea of pairing (Ca, Ba)ZrS₃ with next-generation inorganic spinel hole transport layers (HTLs). We integrated NiCo₂O₄, ZnCo₂O₄, CuCo₂O₄, and SrFe₂O₄ into solar cells and simulated their performance using SCAPS-1D.