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Category: chemistry – Page 7

Catalyst turns methane into bioactive compounds for the first time

Natural gas—one of the planet’s most abundant energy sources—is primarily composed of methane, ethane, and propane. While it is widely burned for energy, producing greenhouse gas emissions, scientists and industries have long sought ways to directly convert these hydrocarbons into valuable chemicals. However, their extreme stability and low reactivity have posed a formidable challenge, limiting their use as sustainable feedstocks for the chemical industry.

Now, a team led by Martín Fañanás at the Center for Research in Biological Chemistry and Molecular Materials (CiQUS) at the University of Santiago de Compostela has developed a groundbreaking method to transform methane and other components into versatile “building blocks” for synthesizing high-demand products, such as pharmaceuticals. Published in Science Advances, this advance represents a critical leap toward a more sustainable and circular chemical economy.

For the first time, the CiQUS team successfully synthesized a bioactive compound—dimestrol, a non-steroidal estrogen used in hormone therapy—directly from methane. This achievement demonstrates the potential of their methodology to create complex, high-value molecules from a simple, abundant, and low-cost raw material.

New lightweight polymer film can prevent corrosion

MIT researchers have developed a lightweight polymer film that is nearly impenetrable to gas molecules, raising the possibility that it could be used as a protective coating to prevent solar cells and other infrastructure from corrosion, and to slow the aging of packaged food and medicines.

The polymer, which can be applied as a film mere nanometers thick, completely repels nitrogen and other gases, as far as can be detected by laboratory equipment, the researchers found. That degree of impermeability has never been seen before in any polymer, and rivals the impermeability of molecularly-thin crystalline materials such as graphene.

“Our polymer is quite unusual. It’s obviously produced from a solution-phase polymerization reaction, but the product behaves like graphene, which is gas-impermeable because it’s a perfect crystal. However, when you examine this material, one would never confuse it with a perfect crystal,” says Michael Strano, the Carbon P. Dubbs Professor of Chemical Engineering at MIT.

Genetically engineered virus acts as ‘smart sponge’ to extract rare earth elements from water

Today’s high-tech electronics and green energy technologies would not function without rare earth elements (REEs). These 17 metals possess unique properties essential to creating items like the phosphors that illuminate our mobile phone displays and the powerful magnets used in electric vehicles and wind turbines. But extracting these substances from raw materials is a dirty process that relies on toxic chemicals and leaves behind polluted waste.

Now, a team of UC Berkeley-led researchers may have solved this problem—thanks to a tiny virus.

As reported in Nano Letters, the researchers genetically engineered a to act like a “smart sponge” that grabs from water, and, with a gentle change in temperature and acidity (pH), releases them for collection. Their unusual, groundbreaking approach could lead to a “clean” biological alternative to traditional extraction methods for REEs and other critical elements.

Algorithms reveal how propane becomes propylene for everyday products

Countless everyday products, from plastic squeeze bottles to outdoor furniture, are derived by first turning propane into propylene.

A 2021 study in Science demonstrated that chemists could use tandem nanoscale catalysts to integrate multiple steps of the process into a single reaction—a way for companies to increase yield and save money. But it was unclear what was happening at the , making it difficult to apply the technique to other key industrial processes.

Researchers at the University of Rochester have developed algorithms that show the key atomic features driving the complex chemistry when the nanoscale catalysts turn propane into propylene.

New enzyme network with competing peptides can make decisions based on external environment

The ability to respond to changing surroundings was once considered exclusive to complex living organisms. Then came computers, specially designed for stimulus–response tasks, which can take in signals from their environment and choose what to do next based on the instructions already written into them.

Scientists have long wanted to replicate this kind of behavior in . Life and computers both need many parts working in sync to make decisions, so expecting a handful of chemicals in a to do the same seemed quite far-fetched.

Not anymore. A team of researchers from the Netherlands and Australia has developed a novel chemical network where different peptides compete for enzymes—specifically proteases arranged in a network. This competition causes the to reorganize itself, forming an enzymatic network that adapts to the external environment.

Nonsurgical treatment shows promise for targeted seizure control

Rice University bioengineers have demonstrated a nonsurgical way to quiet a seizure-relevant brain circuit in an animal model. The team used low-intensity focused ultrasound to briefly open the blood-brain barrier (BBB) in the hippocampus, delivered an engineered gene therapy only to that region and later flipped an on-demand “dimmer switch” with an oral drug.

The research shows that a one-time, targeted procedure can modulate a specific brain region without impacting off-target areas of the brain. It is published in and featured on the cover of ACS Chemical Neuroscience.

“Many are driven by hyperactive cells at a particular location in the brain,” said study lead Jerzy Szablowski, assistant professor of bioengineering and a member of the Rice Neuroengineering Initiative. “Our approach aims the therapy where it is needed and lets you control it when you need it, without surgery and without a permanent implant.”

Nanorobots guide stem cells to become bone cells via precise pressure

For the first time, researchers at the Technical University of Munich (TUM) have succeeded in using nanorobots to stimulate stem cells with such precision that they are reliably transformed into bone cells. To achieve this, the robots exert external pressure on specific points in the cell wall. The new method offers opportunities for faster treatments in the future.

Prof. Berna Özkale Edelmann’s nanorobots consist of tiny gold rods and plastic chains. Several million of them are contained in a gel cushion measuring just 60 micrometers, together with a few . Powered and controlled by , the robots, which look like tiny balls, mechanically stimulate the cells by exerting pressure.

“We heat the gel locally and use our system to precisely determine the forces with which the nanorobots press on the cell—thereby stimulating it,” explains the professor of nano-and microrobotics at TUM. This mechanical stimulation triggers biochemical processes in the cell. Ion channels change their properties, and proteins are activated, including one that is particularly important for bone formation.

First Glimpse of a “Young Sun” Super-Eruption Captured by Astronomers

A young Sun’s violent plasma eruptions may have helped ignite the spark of life on Earth. Astronomers observed a massive, multi-temperature plasma eruption from a young Sun-like star, revealing how early solar explosions could shape planets. These fierce events may have influenced the atmosphere and life-forming chemistry of the early Earth.

Although we rarely notice from Earth, the Sun is continuously hurling enormous clouds of charged plasma into space. These events, known as coronal mass ejections (CMEs), often occur alongside sudden bursts of light called solar flares. When particularly strong, CMEs can stretch far enough to disturb Earth’s magnetic field, producing dazzling auroras and sometimes triggering geomagnetic storms that disrupt satellites or even power grids.

Scientists believe that billions of years ago, when the Sun and Earth were both young, solar activity was far more intense than it is today. Powerful CMEs during that period may have influenced the conditions that allowed life to emerge and evolve. Studies of young Sun-like stars — used as stand-ins for our own star’s early years — show that these stars often unleash flares far stronger than any recorded from the modern Sun.

A Quantum Microscope Reveals Water Breaking Apart

A scheme combining a scanning probe microscope with a quantum sensor can locally trigger water dissociation and observe the elementary steps of such a reaction.

Every experimental technique comes with trade-offs. High-resolution microscopy can pinpoint the positions of individual atoms, yet it typically cannot identify them chemically. Spectroscopy provides chemical information but often only as an averaged signal over a large region. To construct a comprehensive picture of processes at the nanoscale, researchers often resort to combining two or more independent methods. The metaphorical silver bullet would be a single technique that is both local and capable of identifying chemical species as they form and react. Now Wentian Zheng of Peking University and his collaborators have taken an impressive step toward that goal. They have combined two previously separate capabilities—quantum sensing and scanning probe microscopy (SPM)—into a single instrument that can trigger and observe chemical reactions with nanometer resolution [1].

New recharge-to-recycle reactor turns battery waste into new lithium feedstock

As global electric vehicle adoption accelerates, end-of-life battery packs are quickly becoming a major waste stream. Lithium is costly to mine and refine, and most current recycling methods are energy- and chemical-intensive, often producing lithium carbonate that must be further processed into lithium hydroxide for reuse.

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